We still dont know who airs the game. The ACC has contracts with ESPN and a weekly game on CW (for reference, Wake is playing Ole Miss on the CW this weekend). I dont know what pick the CW gets.
If ESPN picks up the game for one of its main (non-ACC) networks, then they will place wherever they feel. If its not placed on a main network, it may be placed on the ACC network (usually time slots of 12pm, 3:30pm, and 8pm, all eastern time). If it isnt placed on ESPN main network, the CW, or ACC network, then it will be on the ACC Extra Network (which I beleive is just ESPN plus, but i could be wrong)